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Publications and Presentations

Select year range: 1978 - 1990 | 1991 - 1995 | 1996 - 1999 | 2000 - 2004

Links to the pdf-version of papers are provided for convenience only. Users must have Acrobat Reader and must have access to the journal sites. The following list of publications can also be downloaded as pdf-file.

:: Research Publications 1978 - 1990

(1) J. P. Richard, H.-T. Ho and P. A. Frey, "Synthesis of Nucleoside [18O] Pyrophosphorothioates with Chiral [18O] Phosphorothioate Groups of Known Configuration. Stereochemical Orientations of Enzymic Phosphorylations of Chiral [18O] Phosphorothioates", Journal of the American Chemical Society, 100, 7756-7757 (1978).

(2) J. P. Richard and P. A. Frey, "Stereochemical Course of the Thiophosphoryl Group Transfer Catalyzed by Adenylate Kinase", Journal of the American Chemical Society, 100, 7757-7758 (1978).

(3) J. P. Richard, D. C. Prasher, D. H. Ives and P. A. Frey, "Chiral [18O] Phosphorothioates: The Stereochemical Course of Thiophosphoryl Group Transfer Catalyzed by Nucleoside Phosphotransferase", Journal of Biological Chemistry, 254, 4339-4341 (1979).

(4) K.-F. R. Sheu, J. P. Richard and P. A. Frey, "Stereochemical Courses of Nucleotidyltransferase and Phosphotransferase Action. Uridine Diphosphate Glucose Pyrophosphorylase, Galactose-1-Phosphate Uridylyltransferase, Adenylate Kinase, and Nucleoside Diphosphate Kinase", Biochemistry, 18, 5548-5556 (1979).

(5) D. H. Pliura, D. Schomburg, J. P. Richard, P. A. Frey and J. R. Knowles, "Stereochemical Course of a Phosphokinase Using a Chiral [18O] Phosphorothioate. Comparison with the Transfer of a Chiral [16O, 17O, 18O] Phosphoryl Group", Biochemistry, 19, 325-329 (1980).

(6) J. P. Richard, M. C. Carr, D. H. Ives and P. A. Frey, "The Stereochemical Course of Thiophosphoryl Group Transfer Catalyzed by Adenosine Kinase", Biochemical and Biophysical Research Communications, 94, 1052-1056 (1980).

(7) J. P. Richard and P. A. Frey, "Synthesis of Chiral (18O) Phosphorothioate Analogs of Adenine Nucleotides", Journal of the American Chemical Society, 104, 3476-3481 (1982).

(8) J. P. Richard and W. P. Jencks, "A Simple Relationship Between Carbocation Lifetime and Reactivity-Selectivity Relationships for the Solvolysis of Ring-Substituted 1‑Phenylethyl Derivatives", Journal of the American Chemical Society, 104, 4689-4691 (1982).

(9) J. P. Richard and W. P. Jencks, "Concerted SN2 Displacement Reactions of 1‑Phenylethyl Chlorides", Journal of the American Chemical Society, 104, 4691-4692 (1982).

(10) J. P. Richard and P. A. Frey, "The Stereochemical Course of Phosphoanhydride Synthesis", Journal of the American Chemical Society, 105, 6605-6609 (1983).

(11) J. P. Richard, M. E. Rothenberg and W. P. Jencks, "Formation and Stability of Ring-Substituted 1-Phenylethyl Carbocations", Journal of the American Chemical Society, 106, 1361-1372 (1984).

(12) J. P. Richard and W. P. Jencks, "Reactions of Substituted 1-Phenylethyl Carbocations With Alcohols and Other Nucleophilic Reagents", Journal of the American Chemical Society, 106, 1373-1383 (1984).

(13) J. P. Richard and W. P. Jencks, "Concerted Bimolecular Substitution Reactions of 1‑Phenylethyl Derivatives", Journal of the American Chemical Society, 106, 1383-1396 (1984).

(14) J. P. Richard and W. P. Jencks, "General Base Catalysis of the Addition of Hydroxylic Reagents to Unstable Carbocations and Its Disappearance", Journal of the American Chemical Society, 106, 1396-1401 (1984).

(15) K.-F. R. Sheu, H.-T. Ho, L. D. Nolan, P. Markovitz, J. P. Richard, M. F. Utter and P. A. Frey, "The Stereochemical Course of Thiophosphoryl Group Transfer Catalyzed by Mitochondrial Phosphoenolpyruvate Carboxykinase", Biochemistry, 23, 1779-1783 (1984).

(16) J. P. Richard, "Acid-Base Catalysis of the Elimination and Isomerization Reactions of Triose Phosphates", Journal of the American Chemical Society, 106, 4926-4936 (1984).

(17) J. P. Richard, "Reaction of Triose Phosphate Isomerase with L-Glyceraldehyde 3-Phosphate and Triose 1,2 Enediol 3-Phosphate", Biochemistry, 24, 949-953 (1985).

(18) M. E. Rothenberg, J. P. Richard and W. P. Jencks, "Equilibrium Constants for the Interconversion of Substituted 1-Phenylethyl Alcohols and Ethers. A Measurement of Intramolecular Electrostatic Interactions", Journal of the American Chemical Society, 107, 1340-1346 (1985).

(19) J. P. Richard, "Surprisingly Small Effect of an α-CF3 for α-CH3 Substitution on 1-(4-Methoxyphenyl)ethyl Cation Reactivity", Journal of the American Chemical Society, 108, 6819-6820 (1986).

(20) J. P. Richard, "Desolvation-Limited Reactions of Amines with the 1-(4-Methylthio-phenyl)-2,2,2-trifluoroethyl Carbocation", Journal of the Chemical Society, Chemical Communications, 1768-1769 (1987).

(21) J. P. Richard, "The Extraordinarily Long Lifetimes and Other Properties of Highly Destabilized Ring-Substituted 1-Phenyl-2,2,2-trifluoroethyl Carbocations", Journal of the American Chemical Society, 111, 1455-1465 (1989).

(22) J. P. Richard, "Reduction of the 1-(4-Methylthiophenyl)-2,2,2-trifluoroethyl Carbocation by Sodium Sulfite", Tetrahedron Letters, 30, 23-26 (1989).

(23) J. P. Richard, "Aromatic Substitution Reactions of Amines with Ring-Substituted 1‑Phenyl-2,2,2-trifluoroethyl Carbocations", Journal of the American Chemical Society, 111, 6735-6744 (1989).

(24) T. L. Amyes and J. P. Richard, "Concurrent Stepwise and Concerted Substitution Reactions of 4-Methoxybenzyl Derivatives and the Lifetime of the 4-Methoxybenzyl Carbocation", Journal of the American Chemical Society, 112, 9507-9512 (1990).

(25) J. P. Richard, T. L. Amyes, L. Bei and V. Stubblefield, "The Effect of b-Fluorine Substituents on the Rate and Equilibrium Constants for the Reactions of a-Substituted 4‑Methoxybenzyl Carbocations and on the Reactivity of a Simple Quinone Methide", Journal of the American Chemical Society, 112, 9513-9519 (1990).



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