Rzayev Research Group

  1. (1) Altay, E.; Nykypanchuk, D.; Rzayev, J. “Mesoporous Polymer Frameworks from End-Reactive Bottlebrush Copolymers”, ACS Nano 2017, 11, 8207. DOI: 10.1021/acsnano.7b03214

  2. (2) Jeong, G.; Yu, D. M.; Mapas, J. K. D.; Sun, Z.; Rzayev, J., Russell, T. P. “Realizing 5.4 nm Full Pitch Lamellar Microdomains by a Solid-State Transformation”, Macromolecules 2017, 50, 7148. DOI: 10.1021/acs.macromol.7b01443

  3. Bullet ACS Editors' Choice

  4. (3) Onbulak, S.; Rzayev, J. “Synthesis and One-Dimensional Assembly of Cylindrical Polymer Nanoparticles Prepared from Tri-Component Bottlebrush Copolymers”, J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 3868. DOI: 10.1002/pola.28771

  5. (4) Unsal, H.; Onbulak, S.; Calik, F.; Er-Rafik, M.; Schmutz, M.; Sanyal, A.; Rzayev, J. “Interplay between Molecular Packing, Core Cross-linking, and Drug Loading in Bottlebrush Copolymer Micelles”, Macromolecules 2017, 50, 1342. DOI: 10.1021/acs.macromol.6b02182

  6. (5) Mapas, J. K. D.; Thomay, T.; Cartwright, A. N.; Ilavsky, J.; Rzayev, J. “Ultrahigh Molecular Weight Linear Block Copolymers: Rapid Access by Reversible-Deactivation Radical Polymerization and Self-Assembly into Large Domain Nanostructures”, Macromolecules 2016, 49, 3733. DOI: 10.1021/acs.macromol.6b00863

  7. (6) Zhang, Y.; Song, W.; Geng, J.; Chitgupi, U.; Unsal, H.; Federizon, J.; Rzayev, J.; Sukumaran, D. K.; Alexandridis, P.; Lovell, J. F. “Therapeutic Surfactant-Stripped Frozen Micelles”, Nature Commun. 2016, 7:11649. DOI: 10.1038/ncomms11649

  8. (7) Altay, E.; Rzayev, J. “Synthesis of Star-Brush Polymer Architectures from End-Reactive Molecular Bottlebrushes”, Polymer 2016, 98, 487. DOI: 10.1016/j.polymer.2016.02.022

  9. (8) Onbulak, S.; Rzayev, J. "Cylindrical Nanocapsules from Photo-Cross-Linkable Core-Shell Bottlebrush Copolymers", Polym. Chem. 2015, 6, 764. DOI: 10.1039/C4PY01215A

  10. (9) Fenyves, R.; Schmutz, M.; Horner, I. J.; Bright, F. V.; Rzayev, J. "Aqueous Self-Assembly of Giant Bottlebrush Block Copolymer Surfactants as Shape-Tunable Building Blocks", J. Am. Chem. Soc. 2014, 136, 7762. DOI: 10.1021/ja503283r

  11. (10) Bolton, J., Rzayev, J. "Synthesis and Melt Self-Assembly of PS-PMMA-PLA Triblock Bottlebrush Copolymers", Macromolecules 2014, 47, 2864. DOI: 10.1021/ma500625k

  12. (11) Luo, K., Xie, T., Rzayev, J. "Synthesis of Thermally Degradable Epoxy Adhesives", J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4992. DOI: 10.1002/pola.26926

  13. (12) Canterbury, D. P.; Huang, K.; Xie, T.; Rzayev, J. "Robust Superhydrophilic Coatings by Electropolymerization of Sulfonated Pyrrole", J. Appl. Polym. Sci. 2013, 127, 257. DOI: 10.1002/APP.37908

  14. (13) Rzayev, J. "Molecular Bottlebrushes: New Opportunities in Nanomaterials Fabrication", ACS Macro Lett. 2012, 1, 1146 (Viewpoint article). DOI: 10.1021/mz300402x

  15. (14) Huang, K.; Johnson, M.; Rzayev, J. "Synthesis of Degradable Organic Nanotubes by Bottlebrush Molecular Templating", ACS Macro Lett. 2012, 1, 892. DOI: 10.1021/mz3002287

  16. (15) Bolton, J.; Rzayev, J. "Tandem ATRP-RAFT Synthesis of Polystyrene-Poly(Methyl Methacrylate) Bottlebrush Block Copolymers and Their Self-Assembly into Cylindrical Nanostructures", ACS Macro Lett. 2012, 1, 15. DOI: 10.1021/mz200003j

  17. (16) Huang, K.; Rzayev, J. "Charge and Size Selective Molecular Transport by Amphiphilic Organic Nanotubes", J. Am. Chem. Soc. 2011, 133, 16726. DOI: 10.1021/ja204296v

  18. Bullet Highlighted in Chemical Engineering Progress, January 2012, 6.

  19. (17) Han, W.; Byun, M.; Zhao, L.; Rzayev, J.; Lin, Z. "Controlled Evaporative Self-Assembly of Hierarchically Structured Bottlebrush Block Copolymer with Nanochannels", J. Mater. Chem. 2011, 21, 14248. DOI: 10.1039/C1JM10978B

  20. (18) Luo, K.; Kim, S. J.; Cartwright, A. N.; Rzayev, J. "Soluble Polyacetylene Derivatives by Chain-Growth Polymerization of Dienes", Macromolecules 2011, 44, 4665. DOI: 10.1021/ma2004713

  21. Bullet Highlighted in Synfacts 2011, 9, 0963. DOI: 10.1055/s-0030-1261014

  22. (19) Huang, K.; Jacobs, A.; Rzayev, J. "De Novo Synthesis and Cellular Uptake of Organic Nanocapsules with Tunable Surface Chemistry", Biomacromolecules 2011, 12, 2327. DOI: 10.1021/bm200394t

  23. (20) Velazquez, J. M.; Gaikwad, A. V.; Rout, T. K.; Rzayev, J.; Banerjee, S. "A Substrate-Integrated and Scalable Templated Approach Based on Rusted Steel for the Fabrication of Polypyrrole Nanotube Arrays", ACS Appl. Mater. Interfaces 2011, 3, 1238. DOI: 10.1021/am2000533

  24. (21) Bolton, J.; Bailey, T. S.; Rzayev, J. "Large Pore Size Nanoporous Materials From the Self-Assembly of Asymmetric Bottlebrush Block Copolymers", Nano Lett. 2011, 11, 998. DOI: 10.1021/nl103747m

  25. Bullet Highlighted in MRS Bulletin 2011, 36 (4), 242. DOI:10.1557/mrs.2011.76; Membrane Technology, March 2011, 8. DOI: 10.1016/S0958-2118(11)70035-0; Chemical Engineering Progress, April 2011, 8.

  26. (22) Huang, K.; Canterbury, D. P.; Rzayev, J. "Synthesis of Segmented Polylactide Molecular Brushes and Their Transformation to Open-End Nanotubes", Macromolecules 2010, 43, 6632. DOI: 10.1021/ma100971w

  27. (23) Huang, K.; Canterbury, D. P.; Rzayev, J. "Organosoluble Polypyrrole Nanotubes From Core-Shell Bottlebrush Copolymers", Chem. Commun. 2010, 46, 6326. DOI: 10.1039/c002447c

  28. (24) Zhao, L.; Byun, M.; Rzayev, J.; Lin Z. "Polystyrene-Polylactide Bottlebrush Block Copolymer at the Air/Water Interface", Macromolecules 2009, 42, 9027. DOI: 10.1021/ma9016345

  29. (25) Luo, K.; Rzayev, J. "Living Radical Polymerization of Bicyclic Dienes: Synthesis of Thermally Cross-linkable Block Copolymers", Macromolecules 2009, 42, 9268. DOI: 10.1021/ma901645t

  30. (26) Huang, K.; Rzayev, J. "Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers", J. Am. Chem. Soc. 2009, 131, 6880. DOI: 10.1021/ja901936g

  31. Bullet Highlighted in Synfacts 2009, 8, 0854. DOI: 10.1055/s-0029-1217472

  32. (27) Rzayev, J. "Synthesis of Polystyrene-Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures", Macromolecules 2009, 42, 2135. DOI: 10.1021/ma802304y

Previous publications of Javid Rzayev:

  1. (28) Bailey, T. S.; Rzayev, J.; Hillmyer, M. A. "Routes to Alkene and Epoxide Functionalized Nanoporous Materials from Poly(styrene-b-isoprene-b-lactide) Triblock Copolymers", Macromolecules 2006, 39, 8772.

  2. (29) Phillip, W. A.; Rzayev, J.; Hillmyer, M. A.; Cussler, E. L. "Gas and Water Liquid Transport Through Nanoporous Block Copolymer Membranes", J. Membrane Sci. 2006, 286, 144.

  3. (30) Guo, S.; Rzayev, J.; Bailey, T. S.; Zalusky, A. S.; Olayo-Valles, R.; Hillmyer, M. A. "Nanopore and Nobushing Arrays from ABC Triblock Thin Films Containing Two Etchable Blocks", Chem. Mater. 2006, 18, 1719.

  4. (31) Rzayev, J.; Hillmyer, M. A. "Nanochannel Array Plastics with Tailored Surface Chemistry", J. Am. Chem. Soc. 2005, 127(38), 13373.

  5. Bullet Highlighted in the News section of Materials Today 2005, 8(11), 15.

  6. (32) Rzayev, J.; Hillmyer, M. A. "Nanoporous Polystyrene Containing Hydrophilic Pores from an ABC Triblock Copolymer Precursor", Macromolecules 2005, 38(1), 3.

  7. Bullet Selected as the Most-Accessed paper in Macromolecules in 2005.

  8. (33) Rzayev, J.; Penelle, J. "HP-RAFT: A Free-Radical Polymerization Technique for Obtaining Living Polymers of Ultra-High Molecular Weights", Angew. Chem. Int. Ed. 2004, 43, 1691; Angew. Chem. 2004, 116, 1723.

  9. (34) Rzayev, J.; Dickinson, L. C.; Penelle, J. "Alternating Free-Radical Isomerization Polymerization of Methyl alpha-Isobutylacrylate", Macromolecules 2003, 36(16), 6273.

  10. (35) Rzayev, J.; Penelle, J. "Controlled/Living Free-Radical Polymerization under Very High Pressure", Macromolecules 2002, 35(5), 1489.

  11. (36) Rzayev, J.; Penelle, J. "Polymerization of Sterically Congested alpha-Alkylacrylates under High Pressure", J. Polym. Sci., Part A: Polym. Chem. 2002, 40(7), 836.